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Abstract Sulfide solid-state electrolytes (SSEs) are promising candidates to realize all solid-state batteries (ASSBs) due to their superior ionic conductivity and excellent ductility. However, their hypersensitivity to moisture requires processing environments that are not compatible with today’s lithium-ion battery manufacturing infrastructure. Herein, we present a reversible surface modification strategy that enables the processability of sulfide SSEs (e. g., Li6PS5Cl) under humid ambient air. We demonstrate that a long chain alkyl thiol, 1-undecanethiol, is chemically compatible with the electrolyte with negligible impact on its ion conductivity. Importantly, the thiol modification extends the amount of time that the sulfide SSE can be exposed to air with 33% relative humidity (33% RH) with limited degradation of its structure while retaining a conductivity of above 1 mS cm-1for up to 2 days, a more than 100-fold improvement in protection time over competing approaches. Experimental and computational results reveal that the thiol group anchors to the SSE surface, while the hydrophobic hydrocarbon tail provides protection by repelling water. The modified Li6PS5Cl SSE maintains its function after exposure to ambient humidity when implemented in a Li0.5In | |LiNi0.8Co0.1Mn0.1O2ASSB. The proposed protection strategy based on surface molecular interactions represents a major step forward towards cost-competitive and energy-efficient sulfide SSE manufacturing for ASSB applications.more » « lessFree, publicly-accessible full text available December 1, 2026
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Free, publicly-accessible full text available November 12, 2025
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ABSTRACT The citation of scientific papers is considered a simple and direct indicator of papers' impact. This paper predicts papers' citations through team‐related variables, team composition, and team structure. Team composition includes team size, male/female dominance, academia/industry collaboration, unique race number, and unique country number. Team structures are made up of team power level and team power hierarchy. Team members' previous citation number, H‐index, previous collaborators, career age, and previous paper numbers are a proxy of team power. We calculated the mean value and Gini coefficient to represent team power level (the collective team capability) and team power hierarchy (the vertical difference of power distribution within a team). Taking 1,675,035 CS teams in the DBLP dataset, we trained the XGBoost model to predict high/low citation. Our model has reached 0.71 in AUC and 70.45% in accuracy rate. Utilizing Explainable AI method SHAP to evaluate features' relative importance in predicting team citation categories, we found that team structure plays a more critical role than team composition in predicting team citation. High team power level, flat team power structure, diverse race background, large team, collaboration with industry, and male‐dominated teams can bring higher team citations. Our project can provide insights into how to form the best scientific teams and maximize team impact from team composition and team structure.more » « less
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null (Ed.)Abstract We show a simple reduction which demonstrates the cryptographic hardness of learning a single periodic neuron over isotropic Gaussian distributions in the presence of noise. More precisely, our reduction shows that any polynomial-time algorithm (not necessarily gradientbased) for learning such functions under small noise implies a polynomial-time quantum algorithm for solving worst-case lattice problems, whose hardness form the foundation of lattice-based cryptography. Our core hard family of functions, which are well-approximated by one-layer neural networks, take the general form of a univariate periodic function applied to an affine projection of the data. These functions have appeared in previous seminal works which demonstrate their hardness against gradient-based (Shamir’18), and Statistical Query (SQ) algorithms (Song et al.’17). We show that if (polynomially) small noise is added to the labels, the intractability of learning these functions applies to all polynomial-time algorithms, beyond gradient-based and SQ algorithms, under the aforementioned cryptographic assumptions. Moreover, we demonstrate the necessity of noise in the hardness result by designing a polynomial-time algorithm for learning certain families of such functions under exponentially small adversarial noise. Our proposed algorithm is not a gradient-based or an SQ algorithm, but is rather based on the celebrated Lenstra-Lenstra-Lovász (LLL) lattice basis reduction algorithm. Furthermore, in the absence of noise, this algorithm can be directly applied to solve CLWE detection (Bruna et al.’21) and phase retrieval with an optimal sample complexity of d + 1 samples. In the former case, this improves upon the quadratic-in-d sample complexity required in (Bruna et al.’21).more » « less
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